Theophylline NCA Case Study
Step-by-Step PK Analysis

Walk through a complete Non-Compartmental Analysis using real Theophylline pharmacokinetic data — the most widely used validation dataset in PK software.

Background: Theophylline

Theophylline is a methylxanthine bronchodilator used in the treatment of asthma and COPD. It has a narrow therapeutic index (10–20 μg/mL), making precise PK characterization essential. The Theophylline Subject 1 dataset from Gabrielsson & Weiner's textbook is one of the most widely used validation datasets in pharmacokinetic software.

Study Details

Drug: Theophylline · Dose: 319.992 mg (oral) · Route: Extravascular
Subject: Subject 1 · Matrix: Plasma · Time Points: 11 samples (0–24.37 h)

1 The Raw Data

Here are the 11 concentration-time data points for Theophylline Subject 1:

PointTime (h)Concentration (ng/mL)Phase
10.000.74Baseline
20.252.84↑ Absorption
30.576.57↑ Absorption
41.1210.50★ Cmax
52.029.66↓ Distribution
63.828.58↓ Distribution
75.108.36↓ Elimination
87.037.47↓ Elimination
99.056.89↓ Elimination
1012.125.94↓ Terminal
1124.373.28↓ Terminal

2 Observed Parameters

Some parameters can be read directly from the data without any computation:

Directly Observed

Cmax
10.50ng/mL
Tmax
1.12h
Clast
3.28ng/mL
Tlast
24.37h

3 AUC Calculation

Using the Linear-up Log-down trapezoidal method:

  • Points 1→4 (ascending): Linear trapezoidal
  • Points 4→11 (descending): Log-linear trapezoidal

Computing each interval and summing gives us the total AUC from time 0 to the last measured time point (24.37 h):

AUC Parameters

AUC₀₋ₜ
147.24ng·h/mL
AUC₀₋∞
214.92ng·h/mL
AUC % Extrap
31.48%
AUMC₀₋ₜ
1498.9ng·h²/mL
High Extrapolation (%AUCextrap = 31.5%)

The extrapolated fraction exceeds the typical 20% threshold. This indicates that the sampling window may not have been long enough to fully characterize the terminal phase. In practice, you would extend sampling or note this caveat when reporting AUC₀₋∞. This is a known characteristic of this particular dataset.

4 Terminal Phase Analysis

PK-Swift's Best Fit algorithm selects the optimal terminal points by evaluating all subsets of ≥ 3 consecutive points after Tmax and choosing the one with the highest adjusted R².

Terminal Phase Regression

λz
0.048461/h
Half-life (t½)
14.30h
R² adjusted
1.0000
Terminal Points
3+

5 Derived PK Parameters

Using dose (319.992 mg), AUC₀₋∞, and λz, we derive:

Derived Parameters

CL/F
1.489L/h
Vz/F
30.72L
MRTlast
10.18h
MRTinf
21.15h

6 Clinical Interpretation

Clinical Significance

Cmax (10.50 ng/mL) — Within the therapeutic range (10–20 μg/mL for theophylline), indicating adequate drug levels for bronchodilation.

Half-life (14.3 h) — Typical for theophylline in adult non-smokers. Smokers typically have shorter half-lives (4–5 h) due to CYP1A2 induction. This long half-life supports once- or twice-daily dosing regimens.

CL/F (1.49 L/h) — Consistent with published values for oral theophylline clearance. Note: this is apparent clearance (CL/F) which includes the effect of bioavailability.

Vz/F (30.7 L) — Theophylline distributes into approximately 0.5 L/kg of body weight, suggesting moderate tissue distribution.

7 Validation Summary

All computed parameters agree with published textbook reference values within expected tolerances. PK-Swift's automated Validation Benchmark runs 18 tests on this exact dataset and achieves >99% geometric mean accuracy.

ParameterComputedReferenceStatus
Cmax10.5010.50✓ PASS
Tmax1.121.12✓ PASS
AUClast147.24147.24✓ PASS
AUCinf214.92214.92✓ PASS
14.3014.30✓ PASS
CL/F1.4891.489✓ PASS
Vz/F30.7230.72✓ PASS

References

  1. Gabrielsson J, Weiner D. Pharmacokinetic & Pharmacodynamic Data Analysis: Concepts and Applications. 5th ed. Stockholm: Swedish Pharmaceutical Press; 2016.
  2. Rowland M, Tozer TN. Clinical Pharmacokinetics and Pharmacodynamics: Concepts and Applications. 4th ed. Philadelphia: Lippincott Williams & Wilkins; 2011.
  3. Gibaldi M, Perrier D. Pharmacokinetics. 2nd ed. New York: Marcel Dekker; 1982.

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